ar X iv : c on d - m at / 9 90 74 36 v 1 2 8 Ju l 1 99 9 Intrinsic localized modes in the charge - transfer - solid PtCl
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چکیده
We report a theoretical analysis of intrinsic localized modes in a quasi-one-dimensional charge-transfer-solid [P t(en) 2 ][P t(en) 2 Cl 2 ](ClO 4) 4 (PtCl). We discuss strongly nonlinear features of resonant Raman overtone scattering measurements on PtCl, arising from quantum intrinsic localized (multi-phonon) modes (ILMs) and ILM-plus-phonon states. We show, that Ra-man scattering data displays clear signs of a non-thermalization of lattice degrees-of-freedom, manifested in a nonequilibrium density of intrinsic localized modes. Adiabatic lattice dynamics is used in a model two-band Peierls-Hubbard Hamiltonian, including a screened Coulomb interaction between neighboring sites. The Hamiltonian is diagonalized on a finite chain. The calculated adiabatic potential for Peierls distortion of the Cl sublattice displays characteristic non-analytic points, related to a lattice-distortion-induced charge transfer. Possible nonadiabatic effects on ILMs are discussed.
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تاریخ انتشار 1999